Article: Comparison of extraction techniques for measuring exchangeable cations in calcareous soils.

Introduction

Cation exchange capacity (CEC) measurement in alkaline soils is complicated by the need to remove soluble cations and the requirement to buffer extraction solution at a pH to prevent soluble carbonates from dissolving (Tucker 1971, 1974; Ross 1995). Method 15C1 from the Australian Soil and Land Survey Handbook Australian Laboratory Handbook of Soil and Water Chemical Methods" (Rayment and Higginson 1992), colloquially known as the Tucker method, is often quoted as the preferred technique for alkaline soils (Rengasamy and Churchman 1999). Due to the high labour requirements of this method, very few routine testing laboratories have adopted it without ...

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