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Article: Synthesis and characterization of a series of 3-methyl-3-{3-[1-methyl-3-aryl-2-triazenyl]propyl} -1-aryl-1-triazenes and related compounds.
- Article from:
- Canadian Journal of Chemistry
- Article date:
- June 1, 2006
- Author:
CopyrightCOPYRIGHT 2006 NRC Research Press. This material is published under license from the publisher through the Gale Group, Farmington Hills, Michigan. All inquiries regarding rights should be directed to the Gale Group. (Hide copyright information)
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Abstract: A series of diazonium salts has been coupled to both secondary nitrogen atoms of the bis-secondary amine, N,N'-dimethyl-1,3-propanediamine (MeNHC[H.sub.2]C[H.sub.2]C[H.sub.2]NHMe), to afford the new bistriazene series, the 3-methyl-3-{3-[1-methyl-3-aryl-2-triazenyl]propyl}-1-aryl-1-triazenes (9). These compounds have been fully characterized by IR and NMR spectroscopy, with supporting data from elemental analysis and high-resolution mass spectrometry. A limited number of model compounds in the N,N-dimethyl-N-{3-[1-methyl-3 -aryl-2-triazenyl]propyl}amine series (10) have been synthesized to aid in the interpretation of the NMR spectra of the bistriazenes (9). A ...