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Article: The energetics of the [X.sub.2] + [X.sup.-] [right arrow] [X.sub.3.sup.-] equilibrium (X = Cl, Br, I) in aqueous and nonaqueous solution.
- Article from:
- Canadian Journal of Chemistry
- Article date:
- December 1, 2006
- Author:
CopyrightCOPYRIGHT 2006 NRC Research Press. This material is published under license from the publisher through the Gale Group, Farmington Hills, Michigan. All inquiries regarding rights should be directed to the Gale Group. (Hide copyright information)
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Abstract: The magnitude of the stability constants (K) for the formation of [X.sub.3.sup.-] from [X.sup.-] and [X.sub.2] (X = Cl, Br, I) in aqueous and nonaqueous solution depends strongly on both X and solvent. Thermodynamic arguments establish that for aqueous solutions this is not the result of differing bond strengths in the [X.sub.3.sup.-] anion but rather depends on the solvation energies of the relevant anions and halogens. The experimental results for K in different organic solvents can also be rationalized in terms which emphasise solvation effects. Electrospray ionization mass spectrometry (ESI-MS) has been used to qualitatively probe relative bond strengths in ...
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