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Article: Grafting on nanoparticles: is solid-state NMR a convenient tool of investigation?(BRIEF COMMUNICATION)(Report)
- Article from:
- JCT Research
- Article date:
- March 1, 2008
- Author:
CopyrightCOPYRIGHT 2008 Federation of Societies for Coatings Technology. This material is published under license from the publisher through the Gale Group, Farmington Hills, Michigan. All inquiries regarding rights should be directed to the Gale Group. (Hide copyright information)
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Introduction
The physicochemical study of organic/inorganic hybrid materials benefits from the latest developments of solid-state NMR. The NMR interactions can be considered as structural "spies," leading to the implementation of multidimensional experiments. The goal is definitely the characterization of the interfaces of hybrid materials, which play a key role in the properties of materials. These interactions are: (i) the chemical shift, which is directly related to the chemical environment of the nuclei. (ii) the homo- and heteronuclear dipolar interactions, which are spatial in nature and related to the internuclear distances. (iii) the scalar through bond J ...