Article: An in-process ultrasonic approach to investigating the relaxation of orientation and disorientation of polymer melts.(Technical report)

INTRODUCTION

It is well known that many properties, such as mechanical and optical properties, of polymer materials are strongly influenced by shear induced molecular orientation occurring under various polymer melt processing conditions. During such macroscopic deformation, the orientation of isotropic network of polymer chain segments becomes anisotropic with ability to adopt different conformations, from a coil to an extended chain. The disorientation is an opposite process to orientation by which the molecular chains recoil gradually after the cessation of shear. Apparently, the developments of molecular orientation and disorientation depend on the relaxation process ...

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