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Free-Radical Acrylic Solution Copolymerization examined in June virtual conference.(FSCT News)(Conference news)
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JCT CoatingsTech
- Article date:
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May 1, 2008
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Copyright informationCOPYRIGHT 2008 Federation of Societies for Coatings Technology. This material is published under license from the publisher through the Gale Group, Farmington Hills, Michigan. All inquiries regarding rights should be directed to the Gale Group. (Hide copyright information)
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Concluding its spring 2008 series of VLCs, the FSCT will examine "Advances in the Study of High Temperature Free-Radical Acrylic Solution Copolymerization" on June 19, 2008. The conference will be presented by Robin Hutchinson, of Queen's University, in Toronto, ON.
Semibatch starved-feed free-radical solution copolymerization is used to produce acrylic resins for solventborne coatings formulations. Mechanisms and rate coefficients for polymerization of methacrylates, acrylates, and styrene under these high temperature conditions are reviewed. Under high temperature starved-feed operating conditions, secondary reactions, such as methacrylate depropagation and acrylate ...
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Kinetics of the free-radical copolymerization of isobornyl methacrylate...
Polymer Engineering and Science;
November 1, 2006 ;
Soule, E.R. Borrajo, J. Williams, R.J.J.;
787 words
......provided a quantitative fitting of polymerization rate curves for systems containing small...description of the presence of a maximum polymerization rate and the variation of its value and...significant changes produced in the polymerization rate of a free-radical crosslinking ...
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A new approach in modeling template polymerization.
Polymer Engineering and Science;
August 1, 1997 ;
Semino, Daniele Polacco, Giovanni Ricciardi, Alessandra;
787 words
......characterized by a strong increase in the polymerization rate if compared to the polymerization...case the template effect on the polymerization rate is less pronounced than in the case...calculate the initial increase in polymerization rate, but not complete conversion versus...
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Mutations in the Saccharomyces cerevisiae RPB1 Gene Conferring...
Genetics;
April 1, 2006 ;
Malagon, Francisco; Kireeva, Maria L; Shafer, Brenda K; Lubkowska, Lucyna; Et al;
787 words
......have strong opposite effects on the intrinsic in vitro polymerization rate of RNAPII. Moreover, the synthetic interactions of these...PlOl8S) is intrinsically arrest prone and has a slower polymerization rate (POWELL and REINES 1996; MASON and STRUHL 2005). Further...
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Styrene polymerization rate increased for high molecular weight polymers
High Performance Plastics;
November 1, 1992 ;
146 words
......styrene, preferably 300 000-1000 000, is obtained. An organic peroxide or hydroperoxide may additionally be present. The polymerization rate is claimed to be increased, thus allowing high molecular weight polymers to be produced in reasonable reaction times...
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The effect of the polymerization rate.(The Working Domain in Reactive...
Polymer Engineering and Science;
March 1, 1997 ;
Goot, A.J. van der Klaassens, S.A. Janssen, L.P.B.M.;
787 words
......paper, special attention is focused on the effect of the polymerization rate on the process of reactive extrusion. The rate of polymerization...is given by Bamford (11). For homopolymerization, the polymerization rate equals: [v.sub.p] = [k.sub.p] [square root of f[k.sub...
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Thermoanalysis and Rheological Behavior of Emulsion Copolymers of Methyl...
Polymer Engineering and Science;
May 1, 2000 ;
JUNGANG, GAO GUODONG, LIU LITING, YANG LIUCHENG, ZHANG;
787 words
......modem plastics technology. The solution copolymerization of MMA with PMI has been studied...have been lacking until now. In solution copolymerization of PMI with other vinyl monomers...monomer's composition [4]. In solution copolymerization of MMA with PMI, the two monomer...
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Acrylic solid surface for polyester solid surface manufacturers.(GUEST...
Solid Surface;
January 1, 2005 ;
Opsahl, Ross;
726 words
......mixing systems and still required ovens to control the polymerization rate; and 3) Benzoyl peroxide two-pack systems for ambient...temperature peroxide systems, as well as used to moderate the polymerization rate to control exotherm. This eliminates the need for heat...
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Hexafluoropropylene plasmas: polymerization rate-reaction parameter...
Polymer Engineering and Science;
October 1, 1996 ;
Silverstein, M.S. Chen, R. Kesler, O.;
787 words
...INTRODUCTION Plasma polymerized films are highly adhering, pin-hole-free, and crosslinked with potential applications in the microelectronics, biomedical, membrane, aerospace, and automotive fields (1-4). The neutral gaseous monomers entering a plasma reactor are fragmented into reactive species as
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EVM acetate elastomer for auto transmission (First of two...
Rubber & Plastics News;
May 14, 2007 ;
787 words
......Pazur, Terence Dee Lanxess Inc. The ethylene co-vinyl acetate copolymers used by the rubber industry are produced by a solution copolymerization of ethylene and vinyl acetate under medium pressures (200-1,000 bar) and mild temperatures (50 to 120[degrees]C)1...
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UV-radiation curing of waterborne acrylate coatings.
JCT Research;
October 1, 2004 ;
Decker, C. Lorinczova, I.;
787 words
......within less than one second to generate a totally insoluble polymer. The influence of a number of critical factors on the polymerization rate and cure extent has been investigated, namely the type of photoinitiator, the chemical structure of the acrylate functionalized...
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Physical properties of epoxy resin self-reinforced with organic rigid-rod...
Polymer Engineering and Science;
September 1, 2007 ;
Lin, S.P. Han, J.L. Chen, R.Z. Yeh, J.T. Hsieh, K.H.;
787 words
......some effects on the IPNs' morphologies, including their compatibility, crosslinking density, the composition, and the polymerization rate of the two components [5]. Various types of polymer composites that combine epoxy resin with polyurethane have been synthesized...
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Japanese Inventors Develop Expandable Styrene Resin Particles
US Fed News Service, Including US State News;
July 16, 2007 ;
340 words
......resin particles are impregnated with an expanding agent before or after completion of the polymerization. Preferably, at a polymerization rate of 60% or higher, the concentration of oxygen in the reaction vessel is kept at 7 volt % or lower." An abstract of the...
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Kinetic study on copolymerization of ethylene and 1-hexene catalyzed by...
Polymer Engineering and Science;
April 1, 2007 ;
Wang, Jianfeng Wang, Li Gao, Haoqi Wang, Wenqin Jiang, Guohua Dong, Xiaocheng Wang, Wei Feng, Lianfang;
787 words
......sequence length distribution of the resultant polymers [8]. Hutchinson et al. [9] simulated the mass and heat transfer, polymerization rate, molecular weights, and particle morphology, and Tuyu Xie et al. [10] developed a model for molecular weight calculations...
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Sulforaphane Inhibits Human MCF-7 Mammary Cancer Cell Mitotic Progression...
The Journal of Nutrition;
September 1, 2004 ;
Jackson, Steven J T; Singletary, Keith W;
787 words
......exposure of purified bovine brain tubulin to relatively high doses of SUL significantly (P < 0.05) inhibited both tubulin polymerization rate (51% of control) and total tubulin polymerization (78% of control) in vitro. Additionally, polymerization of purified...
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Photo polymerization of acrylamide onto calcium carbonate particle...
Polymer Engineering and Science;
July 1, 2004 ;
Gao, Jun He, Guangjian Lei, Jingxin Li, Qiman;
787 words
......of polymerization conversion can reach above 90%. The polymerization rate at a low temperature (40[degrees]C) is considerably lower...60[degrees]C, the temperature has little effect on the polymerization rate, and the polymerization conversion of AAM levels out at...
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