Article: Method for determination of aconitum alkaloids in dietary supplements and raw botanical materials granted AOAC Official Method[SM] status.(For Your Information)(Report)

The diester-diterpene Aconitum alkaloids, viz. aconitine, hypaconitine, and mesaconitine, are highly toxic compounds and commonly present in the aconite roots such as Radix aconiti (Chuanwu), Radix aconiti kusnezoffii (Caowu), and Radix aconiti lateralis (Fuzi; see figure). Many dietary supplements for enhancing circulation, restoring health, and relieving pain contain processed aconite roots, and thus the Aconitum alkaloids. Proper processing by heating, steaming, and soaking of the aconite roots can hydrolyze the highly toxic diester-diterpene Aconitum alkaloids to compounds of much lower toxicity, e.g., benzoylaconine, benzoylmesaconine, and benzoylhypaconine. ...

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