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Article: Research from X. Zhu and co-authors provides new data about chemical research.
- Article from:
- Ecology, Environment & Conservation
- Article date:
- October 23, 2009
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"Autoxidation of linoleic acid (LA) enhanced by Fe(II)/ascorbate generates unsaturated hydroperoxides which undergo further oxidative evolution resulting in a mixture of electrophiles, including epoxyketooctadecenoic acid and dienones with intact C-18 chains as well as oxidative cleavage products such as 4-hydroxy-2(E)-nonenal (HNE), 4-oxo-2(E)-nonenal (ONE), 2(E)-octenal, 9-hydroxy-12-oxo-10(E)-dodecenoic acid, 9,12-dioxo-10(E)-dodecenoic acid, and 11-oxoundec-9(E)-enoic acid. Mass spectrometric (MALDI-TOF-MS and LC-ESI-MS/MS) studies have been performed following incubation of the model protein beta-lactoglobulin with LA, Fe(II), and ascorbate, which identified adducts ...
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Article: New chemical research from University of ...
Chemicals & Chemistry;
July 21, 2008 ;
700+ words
... ... BINOLate)(3)Ln(THF) [Ln = La, Pr, and Eu], Li-3(py ... PY)(5)(BINOLate)(3)La(py)(2) [py = pyridine ... THF)(n)(BlNOLate)(3)La, is often the most enantioselective ... Philadelphia, Life Sciences, Chemical Research, University of Pennsylvania ...
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