Article: Research from V. Larraillet and co-authors yields new data on proteomics.

According to recent research from Paris, France, "Multiply deprotonated anions [M - nH](n-)of large peptide mellitin, ubiquitin, and beta-casein proteins were subjected to laser irradiation at 260 nm in a quadrupole ion trap. For all compounds, the predominant event consecutive to laser irradiation was the detachment of an electron."

"The subsequent isolation and collisional activation of the oxidized [M - nH]((n-1)-center dot) resulted in extensive fragmentation of the peptide backbone. For mellitin peptide, nearly a complete series of c(center dot), z, and a(center dot), x product ions were observed. Applied to proteins, this technique, coined as ...

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