The interfacial tension between a thermotropic liquid crystalline copolyester and polyethersulfone: a comparison of methods.

Three dynamic methods to determine the interfacial tension between the thermotropic liquid crystalline polymer (TLCP) Vectra A900 and polyethersulfone were evaluated: 1) thread breakup, 2) fiber retraction and 3) dynamic shear rheometry. The thread breakup and retraction methods, were suitable for measuring the interfacial tension, provided that the shear thinning flow behavior of the TLCP was taken into account. The viscosity of the TLCP during breakup or retraction was estimated from steady-shear measurements at the observed overall rate of deformation during growth of capillary instabilities or during retraction. The calculation of the interfacial tension from breakup rates of TLCP ...

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