Article: Crystallization Kinetics of Poly(butylene terephthalate) (PBT): Influence of Additives and Free Carboxylic Acid Chain Ends.

Degradation of poly(butylene terephthalate) (PBT) induced by blending time at 260[degrees]C leads to an increase of both carboxylic end groups and melt viscosity index and a decrease of the molecular weights. Crystallization kinetics of pure PBT and PBT blended with an epoxide, which was used to reduce the free carboxylic acid concentration, were compared. Lower carboxylic acid concentrations were obtained, but the molecular weights still decreased. The crystallization kinetics of PBT blended with pigments and/or mineral fillers were also studied. Dyes, some of which are known for their nucleation activity, were used for differentiating extruded PBT tubes in optical fiber ...

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