Article: PLATING CLINIC.(Brief Article)

Polarized Zinc Anodes

Q. Our shop uses an alkaline, non-cyanide zinc plating bath. We have an on-going problem with the anodes polarizing. What are we doing wrong? M.J.

A. High anode current density and/or low sodium hydroxide usually cause polarization of zinc anodes. The alkaline zinc plating bath has higher anode efficiency than cathode efficiency. This means that if you maintain a 1:1 anode-cathode ratio the amount of zinc in the plating bath will climb. The standard solution to this problem is to remove some of the zinc anodes. This causes the anode current density to climb and the anode will polarize unless the removed zinc anodes are replaced with ...

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