Article: Structures and Properties of Wet Spun Thermo-Regulated Polyacrylonitrile-Vinylidene Chloride Fibers

Abstract Thermo-regulated polyacrylonitrile-vinylidene chloride (PAN/VDC) fibers containing 4-40 wt.% of micro phase-change materials (microPCMs) were wet-spun. In this study, fibers containing less than 30 wt.% of microencapsulated n-octadecane were spun smoothly. The structures and properties of the fibers were investigated by using Fourier transform infrared, scanning electron microscopy, differential scanning calorimetry, wide-angle X-ray diffraction, dynamic mechanical analysis and thermogravimetric analysis, etc. The microcapsules were intact and evenly distributed inside the polymer matrix. The tensile strengths of the fibers with titers in the range of 1.9 to 10.9 dtex were 0.7 to ...

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