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The Characteristic Curvature of Ionic Surfactants
- Article from:
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Journal of Surfactants and Detergents
- Article date:
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July 1, 2008
- Author:
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Copyright informationCopyright AOCS Press Jul 2008. Provided by ProQuest LLC. (Hide copyright information)
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Abstract
Characterizing the hydrophilic-lipophilic nature of a surfactant molecule has been a challenge for colloid scientists and technologists. The hydrophilic-lipophilic balance (HLB), the packing factor, the phase inversion temperature (PIT) and the natural curvature of the surfactant are all terms that seek to address this issue. In this article we build on the hydrophilic-lipophilic difference concept (HLD) (Salager et al. Langmuir, 16, 5534-5539, 2000) to develop a methodology to determine a characteristic curvature (Cc) for ionic surfactants based on the phase behavior of mixed ionic surfactant microemulsions. In essence, the method consists of evaluating the shift in optimal ...
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